I find, for myself, it helps to read books that heavily rely on these sorts of characters, like TAS mentioned. When I can see how other authors did it then I can use some of the same techniques.
The Collector by John Fowles is a short read, but pretty good for the getting into the MC's head (who is a sociopath who loves a girl and kidnaps her).
The Tell-Tale Heart by A.E. Poe is an obvious example, but a really good one.
And my all time favourite villain, Junior Kane, in Dean Koontz' masterpiece From the Corner of his Eye is really well described and the reader spends quite a bit of time in his head.
What I like about these three examples is that the entire time the villain justifies to himself why what he is doing is right. You understand his motives (even though they are warped) and you see him as rounded, albeit crazy. They aren't just evil for evil's sake.
The Collector by John Fowles is a short read, but pretty good for the getting into the MC's head (who is a sociopath who loves a girl and kidnaps her).
The Tell-Tale Heart by A.E. Poe is an obvious example, but a really good one.
And my all time favourite villain, Junior Kane, in Dean Koontz' masterpiece From the Corner of his Eye is really well described and the reader spends quite a bit of time in his head.
What I like about these three examples is that the entire time the villain justifies to himself why what he is doing is right. You understand his motives (even though they are warped) and you see him as rounded, albeit crazy. They aren't just evil for evil's sake.
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